Patent · US Expired

Process for concurrent selective hydrogenation of acetylenes and 1,2 butadine in hydrocarbon streams

US5877363A · kind A · utility

74Cited by
39References
17Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 23, 1996
Grant dateMar 2, 1999
Priority date
Expiry dateSep 23, 2016

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S203/06
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A process for the removal of vinylacetylene, ethylacetylene and 1,2-butadiene from C.sub.4 aliphatic hydrocarbon streams comprising, concurrently: (1) feeding hydrogen and a hydrocarbon stream comprising C.sub.4 hydrocarbons including butanes, butenes, butadienes and vinylacetylene to a distillation column reactor containing a bed comprising a hydrogenation catalyst of the type characterized by platinum, palladium or rhodium which is prepared as a distillation structure to selectively hydrogenate a portion of the vinylacetylene and the 1,2-butadiene and (2) fractionally distilling the reaction mixture to remove a heavier fraction and removing a fraction overhead comprising substantially all of the C.sub.4.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.