Patent · US Expired

Polymerisation of cyclosiloxanes

US5883215A · kind A · utility

16Cited by
5References
11Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 20, 1998
Grant dateMar 16, 1999
Priority date
Expiry dateFeb 20, 2018

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G77/08
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A process for the ring-opening polymerisation of cyclosiloxanes, which comprises contacting a cyclosiloxane with 1-500 ppm by weight of a phosphazene base, based on the weight of cyclosiloxane, in the presence of water, preferably 0.5-10 mols per mol of phospazene base. Also claimed is a process in which the cyclosiloxane is present together with an agent which inhibits catalyst activity of the phosphazene base, e.g. carbon dioxide or water, in which the polymerisation is initiated by reducing the effect of the inhibiting agent e.g. by heating.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.