Patent · US Expired

Catalyst system for the polymerization of olefins, process for this polymerization and polymers thus obtained

US5891976A · kind A · utility

38Cited by
6References
13Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 9, 1997
Grant dateApr 6, 1999
Priority date
Expiry dateJun 9, 2017

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S526/901
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Catalyst systems comprising, on the one hand, a catalytic solid based on complexed titanium trichloride and, on the other hand, a nonhalogenated organoaluminium activator. When employed in gas phase olefin polymerization processes, these catalyst systems make it possible to manufacture a wide range of homopolymers and copolymers (random and block) with an isotacticity index which can be adjusted to very low values and with excellent pourability, even in the case of copolymers of high comonomer content. In the absence of transfer agents they also make it possible to synthesize polymers of very high molecular masses, with an increased activity. These polymerization processes yield particularly advantageous results in the case of propylene.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.