Phosphorus modified small pore molecular sieve catalysts, and their use in the production of light olefins
US5925586A · kind A · utility
Assignee
Inventor
Key dates
| Filing date | Oct 3, 1997 |
| Grant date | Jul 20, 1999 |
| Priority date | — |
| Expiry date | Oct 3, 2017 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P30/40
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A process for the modification of a small pore molecular sieve catalyst to increase its selectivity to ethylene in the production of light olefins from oxygenated compounds, particularly methanol. The catalyst is modified with phosphorus by incorporating a phosphonitrilic oligomer with the catalyst, and then calcining the catalyst at temperature sufficient to decompose the phosphonitrilic oligomer, and deposit from about 0.001 wt. % to about 50 wt. % phosphorus on the catalyst. This modification provides a novel composition in that it increases the ethylene selectivity of the catalyst in the production of light olefins from oxygenates as contrasted with a small pore molecular sieve catalyst otherwise similar except that it has not been so treated and modified with the phosphonitrilic oligomer.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.