Patent · US Expired

Ethylene/alpha-olefin copolymer

US5955639A · kind A · utility

11Cited by
11References
20Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 29, 1993
Grant dateSep 21, 1999
Priority date
Expiry dateJul 29, 2013

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/52
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

A copolymer of ethylene and an alpha-olefin having an ethylene content of from 30 to 90 mole %, a number average molecular weight of from 300 to 30,000 and a molecular weight distribution defined by a Q value (the ratio of the weight average molecular weight to the number average molecular weight) of not more than 3 and a Z value (the ratio of the maximum value of the molecular weight to the minimum value of the molecular weight when the molecular weight is measured by gel permeation chromatography) of from 15 to 200. The said copolymer can be produced by a process comprising copolymerizing ethylene with an alpha-olefin in the liquid phase in the presence of a polymerization catalyst composed of a combination of a soluble vanadium compound and an organoaluminum compound in the co-presence of hydrogen, characterized in that PA1 (a) the copolymerization is carried out in a continuous manner, PA1 (b) the concentration of the vanadium compound in the polymerization system is maintained at 0.3 to 30 millimoles/liter, and PA1 (c) the vanadium compound is supplied to the polymerization system as a solution in a polymerization medium in a concentration which is 1 to 5 times the concentrati…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.