Process of producing polythiol oligomer
US5961889A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Apr 25, 1997 |
| Grant date | Oct 5, 1999 |
| Priority date | — |
| Expiry date | Apr 25, 2017 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08G75/14
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
A process for producing a polythiol oligomer having disulfide linkages by reacting polythiol (with the functionality of two or above) with sulfur in a molar ratio of m to (m-1) (where m is an integer of 2 to 21) in the presence of a basic catalyst, whereby the oligomers produced have a degree of oligomerization of m (wherein m is defined as above). Specifically disclosed is a process for reacting 2,5-dimercaptomethyl-1,4-dithiane (DMMD) with sulfur in a molar ratio 2:1 or 3:2 in the presence of a basic catalyst, thereby producing an oligomer represented by the below formula: ##STR1## (wherein n is an integer of up to 21). Also disclosed are optical polymers made with the oligomer and optical materials and devices made with the polymer.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.