Nanocrystalline Mg or Be-based materials and use thereof for the transportation and storage of hydrogen
US5964965A · kind A · utility
Assignees
Inventors
Key dates
| Filing date | Aug 15, 1997 |
| Grant date | Oct 12, 1999 |
| Priority date | — |
| Expiry date | Aug 15, 2017 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S420/90
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
Disclosed is a very light-weight, Mg and Be-based material which has the ability to reversibly store hydrogen with very good kinetics. This material is of the formula (M.sub.1-x A.sub.x) D.sub.y wherein M is Mg, Be or a combination of them; A is an element selected from the group consisting of Li, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Al, Y, Zr, Nb, Mo, In, Sn, O, Si, B, C and F; D is a metal selected from the group consisting of Fe, Co, Ni, Ru, Rh, Pd, Ir and Pt (preferably Pd); x is a number ranging from 0 to 0.3; and y is a number ranging from 0 to 0.15. This material is in the form of a powder of particles of the formula M.sub.1-x A.sub.x as defined hereinabove, having an average size ranging from 0.1 to 100 .mu.m, each particle consisting of nanocrystalline grains having an average size of 3 to 100 nm or having a nano-layered structure with a layer spacing of 3 to 100 nm. Some of these particles have clusters of metal D attached thereto, with an average size ranging from 2 to 200 nm. Also disclosed are a process for preparing this material which has a very high hydrogen absorption capacity, and a method of use of the same for the transportation and/or storage of hydrogen and/…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.