Patent · US Expired

Process for suspension polymerization of vinyl chloride with carboxyl containing polyvinyl-alcohol

US5977273A · kind A · utility

7Cited by
5References
4Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 8, 1998
Grant dateNov 2, 1999
Priority date
Expiry dateMay 8, 2018

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F8/12
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A dispersing stabilizer suitable for suspension polymerization of vinyl chloride or a monomer mixture mainly composed of vinyl chloride which can be used in a hot water charging polymerization process without any problems, and which can produce vinyl chloride homopolymer or copolymers having a good porosity, a large bulk density, a very low content of coarse particles and good physical properties, the dispersing stabilizer comprising a polyvinyl alcohol having a degree of hydrolysis of 75 to 85% by mole, an absorbance of not less than 0.1 measured at a wavelength of 280 m.mu.with respect to the 0.1% by weight aqueous solution, a content of carboxyl group of 0.01 to 0.15% by mole and a cloud point of not less than 50.degree. C. measured with respect to the 0.1% by weight aqueous solution

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.