Catalysts for hydroxylation and ammination of aromatics using molecular oxygen as the terminal oxidant without coreductant
US5981424A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jul 31, 1997 |
| Grant date | Nov 9, 1999 |
| Priority date | — |
| Expiry date | Jul 31, 2017 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/50
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
Catalyst compositions are disclosed which are useful for the hydroxylation and the ammination of aromatic hydrocarbons using molecular oxygen as terminal oxidant. The catalysts comprise a support selected from the group consisting of metal oxides, molecular sieves, zeolites and clays; transition metal selected from the group consisting of vanadium, niobium, copper, palladium, nickel and silver, and combinations thereof; and at least one multidentate chelating, binucleating ligand. The catalysts may further comprise additional metal ions. The process is particularly suited, for example, to the one-step conversion of benzene to phenol and of benzene to aniline.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.