Patent · US Expired

Bridged metallocenes for use in catalyst systems

US6002033A · kind A · utility

49Cited by
3References
21Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 12, 1998
Grant dateDec 14, 1999
Priority date
Expiry dateJun 12, 2018

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S526/943
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Bridged metallocenes of Group IVb metals provide improved results when the bridge comprises a neutral electron-donor substituent of general formula EQU R'" Z R"".sub.j wherein PA1 R'" is a rigid unsaturated hydrocarbon radical between Z and the bridge, such that Z is separated from the bridge by 2 to 5 carbon atoms PA1 Z is nitrogen, phosphorus, oxygen or sulphur, PA1 R"" is H or an alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl having a maximum of 15 carbon atoms, each R"" being the same or different, PA1 j is 1 when Z=O or S and 2 when Z=N or P.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.