Method and Ru,Re,Sn/carbon catalyst for hydrogenation in aqueous solution
US6008384A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Mar 3, 1998 |
| Grant date | Dec 28, 1999 |
| Priority date | — |
| Expiry date | Mar 3, 2018 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/582
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
An improved two step (dual stage catalysis) aqueous hydrogenation process and a novel trimetallic hydrogenation catalysts consisting essentially of highly dispersed, reduced ruthenium and rhenium metals in the presence of a third metal tin on carbon support particular useful in the second stage of the process. Such process and catalyst exhibit high conversion rates in aqueous solution hydrogenation of hydrogenatable precursors (e.g., maleic acid, succinic acid, corresponding esters, .gamma.-butyrolactone, etc.) to tetrahydrofuran, .gamma.-butyrolactone, 1,4-butanediol and mixtures thereof wherein the relative molar ratio of 1,4-butanediol to tetrahydrofuran products being produced can be controlled.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.