Process for the hydroxycarbonylation of pentenoic acids
US6008408A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jul 11, 1995 |
| Grant date | Dec 28, 1999 |
| Priority date | — |
| Expiry date | Jul 11, 2015 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/584
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
The present invention relates to a process for the hydroxycarbonylation of pentenoic acids. By the process, one or a number of pentenoic acids are hydroxycarbonylated to adipic acid, by carbon monoxide and water, in the presence of a catalyst based on iridium and/or rhodium and of at least one iodinated promoter. The reaction mixture obtained is subjected to a refining operation, after having optionally been concentrated, making it possible to separate at least a part of the catalyst. The catalyst thus separated is recycled to an operation for the hydroxycarbonylation of pentenoic acids, of butadiene, or of butadiene derivatives.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.