Patent · US Expired

Process for the hydroxycarbonylation of pentenoic acids

US6008408A · kind A · utility

1Cited by
1References
17Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 11, 1995
Grant dateDec 28, 1999
Priority date
Expiry dateJul 11, 2015

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/584
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The present invention relates to a process for the hydroxycarbonylation of pentenoic acids. By the process, one or a number of pentenoic acids are hydroxycarbonylated to adipic acid, by carbon monoxide and water, in the presence of a catalyst based on iridium and/or rhodium and of at least one iodinated promoter. The reaction mixture obtained is subjected to a refining operation, after having optionally been concentrated, making it possible to separate at least a part of the catalyst. The catalyst thus separated is recycled to an operation for the hydroxycarbonylation of pentenoic acids, of butadiene, or of butadiene derivatives.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.