Process for fabricating conformal Ti-Si-N and Ti-B-N based barrier films with low defect density
US6017818A · kind A · utility
Assignee
Inventor
Key dates
| Filing date | Jan 21, 1997 |
| Grant date | Jan 25, 2000 |
| Priority date | — |
| Expiry date | Jan 21, 2017 |
Classification
- Technology area (CPC H)Electricity
- CPC primaryH01L21/76843
- WIPO fieldSemiconductors
- WIPO sectorElectrical engineering
Abstract
A CVD process for Ti--Si--N or Ti--B--N films wherein a single feed gas (preferably TDMAT) serves as the source for titanium and nitrogen, and another feed gas is used as the source for silicon or boron. This avoids gas-phase particulate nucleation while providing good conformality. When the required thickness has been deposited, the silicon or boron feed gas continues to flow for some time after the titanium/nitrogen or titanium/boron source gas has been turned off. This results in a Ti--N film with a Si-rich or B-rich surface, which is conformal and has a low defect density. In a second embodiment, a single feed gas, such as TDMAT, is thermally decomposed to form a Ti--N layer. A post-deposition anneal is performed in a gas which supplies silicon or boron, incorporating these materials into the layer. The incorporation of silicon or boron into the layer minimizes the absorption of oxygen into the films, and therefore stabilizes the resulting films. The Si-rich or boron-rich surfaces are also helpful in wetting Al and enhancing adhesion to Cu, therefore are advantageous for advanced metallization application. Compared with the sputtering method, this invention offers a process for…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.