Patent · US Expired

Photochromic organic materials

US6034193A · kind A · utility

18Cited by
39References
20Claims
0Family size

Assignee

Inventors

Key dates

Filing dateOct 10, 1997
Grant dateMar 7, 2000
Priority date
Expiry dateOct 10, 2017

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG02B5/23
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

The invention relates to photochromic transparent organic materials presenting an index of refraction of more than 1.55, which are free of optical distortions and are prepared by radical polymerization of a polymerizable composition comprising: PA1 a) 80-95 wt % of at least one monomer represented by the general formula (I): ##STR1## where R=H or CH.sub.3, and m and n are independently 1 or 2; b) 5-20 wt % of at least one aromatic monovinyl monomer represented by the general formula (II): ##STR2## c) an effective quantity of at least one dye that imparts photochromic properties to the material, selected from the groups of spiroxazines, spiropyrans and chromenes; PA1 d) an effective quantity of a chain transfer agent; and PA1 e) an effective quantity of a radical polymerization initiator, characterized in that the chain transfer agent is a linear alkanethiol and the radical polymerization initiator is a diazo compound.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.