Patent · US Expired

Producing method for trimethylolalkane

US6034284A · kind A · utility

3Cited by
7References
16Claims
0Family size

Assignee

Inventors

Key dates

Filing dateOct 20, 1998
Grant dateMar 7, 2000
Priority date
Expiry dateOct 20, 2018

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C29/38
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

High quality trimethylolalkane can be easily and efficiently produced at a high yield through a reaction between n-alkanal and formaldehyde in the presence of tertiary amine and water, in which a reaction mixture obtained after the reaction is heated up to a temperature at which a salt of tertiary amine with formic acid produced as a by-product can be thermally dissociated so as to distill tertiary amine and water from the reaction mixture, and a formate of trimethylolalkane produced in the distillation of tertiary amine and contained in a residue is reacted with water, ammonia, primary amine or secondary amine; and the tertiary amine distilled from the reaction mixture is reused in producing trimethylolalkane.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.