Patent · US Expired

Process for the production of carbonyl compound

US6066762A · kind A · utility

30Cited by
7References
24Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 23, 1997
Grant dateMay 23, 2000
Priority date
Expiry dateDec 23, 2017

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C51/12
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A process for the production of a carbonyl compound such as acetic acid by reacting a carbonylatable compound such as methanol with a carbon monoxide in the presence of a carbonylation catalyst containing a noble metal complex supported on a porous, cross-linked vinylpyridine resin at a temperature of 140-250.degree. C., a carbon monoxide partial pressure of 7-30 kg/cm.sup.2 and a hydrogen partial pressure of 0.1-5 kg/cm.sup.2 to obtain a liquid product containing the carbonyl compound and an unreacted CO-containing gas product. The water content and the carbonylation degree of the liquid product within the reactor are maintained at 0.5-10% by weight and 0.5-0.9, respectively, The carbonyl compound is separated from the liquid product in a flasher and/or a distillation tower formed of titanium or a titanium-palladium alloy. The liquid product is introduced into a pressure reducing valve and then mixed with the CO-containing gas product before being fed to the flasher and/or distillation tower.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.