Lithium and manganese double oxides for the positive electrodes of electrochemical devices, preparation thereof, and electrodes including such oxides
US6071647A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Oct 17, 1997 |
| Grant date | Jun 6, 2000 |
| Priority date | — |
| Expiry date | Oct 17, 2017 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/10
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
The invention relates to a method of preparing an oxide of formula Li.sub.x Mn.sub.y O.sub.z, in which x lies in the range 0 to 2, y lies in the range 1 to 3, and z lies in the range 3 to 4.5, x, y, and z being such that the oxide has a composition close to LiMn.sub.2 O.sub.4. According to the invention, the method comprises the following steps: PA1 a) a polymer complex of lithium and of manganese is prepared in the form of a gel or of a xerogel by causing a reducing polymer, copolymer or polymer mixture possessing complexing functions for lithium and manganese to react in a common solvent with an oxidizing lithium salt and with an oxidizing manganese salt, and by evaporating off the solvent, partially or in full; and PA1 b) the resulting lithium and manganese polymer complex is mineralized by the explosive oxidation-reduction technique to recover fine amorphous particles of the oxide of formula Li.sub.x Mn.sub.y O.sub.z.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.