Method and catalyst for catalytically oxidizing a low concentration of H.sub.2 S in a gas to give sulphur
US6083471A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Nov 19, 1997 |
| Grant date | Jul 4, 2000 |
| Priority date | — |
| Expiry date | Nov 19, 2017 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S502/517
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A process for catalytically oxidizing the H.sub.2 S present at low concentration in a gas to sulphur wherein the gas together with a gas containing free oxygen in a quantity to provide and O.sub.2 to H.sub.2 S mole ratio ranging from 0.05 to 10 are contacted with a catalyst for selectively oxidizing H.sub.2 S to sulphur, the catalyst comprising a support based on silicon carbide associated with a catalytic active phase containing at least one transition metal such as Fe, Ni, Cr, Co, Cu, Ag, Mn, Mo, Ti, W or V, in a form of a metal compound and/or in the elemental state. Prior to treating the gas, the oxidation catalyst is subjected to an activation treatment which loads the active phase of the catalyst to provide maximum sulphurization of the metal of the catalyst. In an alternate embodiment, the oxidation of the H.sub.2 S is performed below the dew point of the sulphur. In another embodiment, the oxidation is performed at a temperature above the dew point of sulphur and in particular between 200.degree. C. and 500.degree. C. Also disclosed is a catalyst for selectively oxidizing H.sub.2 S to sulphur which comprises a catalytically active phase based on at least one transition meta…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.