Patent · US Expired

Supported mercaptosulfonic acid compounds useful as catalysts for phenolation reactions

US6133190A · kind A · utility

22Cited by
40References
3Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMar 23, 1999
Grant dateOct 17, 2000
Priority date
Expiry dateMar 23, 2019

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C2603/18
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A catalyst useful for the condensation of an aldehyde or ketone starting material with a phenol is an insoluble mercaptosulfonic acid compound. The heterogeneous catalysts comprise catalytically-active species represented by the formula: ##STR1## L is an optional linking group and--is a bond, which catalytically-active species is attached by the bond--to an insoluble organic or inorganic support; PA1 or a catalytically-active species represented by the formula: ##STR2## wherein L' is an optional linking group,--is a bond and .theta.' and .theta." are residues of .theta., and a and b are independently selected from integers equal to or greater than 1.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.