Photocatalytic oxidation of organics using a porous titanium dioxide membrane and an efficient oxidant
US6136186A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jul 14, 1998 |
| Grant date | Oct 24, 2000 |
| Priority date | — |
| Expiry date | Jul 14, 2018 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S210/908
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A method and apparatus for mineralizing organic contaminants in water or air provides photochemical oxidation in a two-phase or three-phase boundary system formed in the pores of a TiO.sub.2 membrane in a photocatalytic reactor. In the three-phase system, gaseous (liquid) oxidant, liquid (gaseous) contaminant, and solid semiconductor photocatalyst meet and engage in an efficient oxidation reaction. The porous membrane has pores which have a region wherein the meniscus of the liquid varies from the molecular diameter of water to that of a capillary tube resulting in a diffusion layer that is several orders of magnitude smaller than the closest known reactors. The photocatalytic reactor operates effectively at ambient temperature and low pressures. A packed-bed photoreactor using photocatalyst coated particles is also provided.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.