Conversion process of hydrocarbon oils

US6156190A · kind A · utility

Assignees

• CHINA PETROCHEMICAL CORPORATION
• RESEARCH INSTITUTE OF PETROLEUM PROCESSING · CN

Inventors

• Guofu Xia · Beijing, CN
• Mei Zhu · Paris, FR
• Enze Min · Beijing, CN
• Yahua Shi · Beijing, CN
• Zhiping Tao · Beijing, CN
• Guici Pang · Beijing, CN
• Mingfeng Li · Lo Wu, CN
• Guopeng Ran · Beijing, CN
• Haitao Huang · Beijing, CN
• Runqiang Zhang · Beijing, CN
• Jian Li · Hubei, CN
• Hong Nie · Longbeilingcun, CN

Key dates

• Filing date: Mar 19, 1999
• Grant date: Dec 5, 2000
• Expiry date: Mar 19, 2019

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C10G69/06
• WIPO field: Basic materials chemistry
• WIPO sector: Chemistry

Abstract

A conversion process of hydrocarbon oils comprises at least a hydrodemercaptanization process, wherein said hydrodemercaptanization process comprises contacting a feedstock with a hydrofining catalyst containing a tungsten oxide and/or a molybdenum oxide, a nickel oxide and a cobalt oxide supported on an alumina under the conditions of hydrodemercaptanization, in which the content of said tungsten oxide and/or molybdenum oxide is from 4 wt % to less than 10 wt %, the nickel oxide content is 1-5 wt %, the cobalt oxide content is 0.01-1 wt % based on the catalyst, and the ratio of total atom number of nickel and cobalt to total atom number of nickel, cobalt, tungsten and/or molybdenum is 0.3-0.9. Said process can be carried out at a lower temperature and a lower H/oil volume ratio.