.alpha.-Olefin/vinylidene aromatic monomer and/or hindered aliphatic or cycloaliphatic vinylidene monomer interpolymers
US6191245A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Mar 2, 1999 |
| Grant date | Feb 20, 2001 |
| Priority date | — |
| Expiry date | Mar 2, 2019 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S526/943
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The present invention relates to .alpha.-olefin/vinyl aromatic monomer interpolymers with characteristic signals in their carbon 13 NMR spectra. In particular, ethylene/styrene copolymers of the present invention have peaks in the carbon 13 NMR spectra which appear in the chemical shift range 43.70-44.25 ppm, preferably from 43.75-44.25 ppm and 38.0-38.5 ppm, said peaks being at least three times the peak to peak noise. The interpolymers are prepared by polymerizing the appropriate mixture of monomers in the presence of a catalyst such as racemic-(dimethylsilanediyl(2-methyl-4-phenylindenyl)) zirconium dichloride. The polymers of the present invention posses increased modulus as determined from both tensile stress/strain and dynamic mechanical data at comparable vinyl aromatic monomer levels.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.