Patent · US Expired

Acrylic flexible light pipe of improved photo-thermal stability

US6207747A · kind A · utility

1Cited by
7References
8Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 11, 1997
Grant dateMar 27, 2001
Priority date
Expiry dateDec 11, 2017

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T428/2933
  • WIPO fieldOther special machines
  • WIPO sectorMechanical engineering

Abstract

Acrylic light pipe has adequate thermal and photo-thermal stability for many purposes, but is deficient in maintaining clarity, color, and good optical properties under conditions of exposure to high temperatures, especially in combination with exposure for lengthy periods to passage of light. Improved thermal stability, as reflected in reduced color formation, can be imparted by adjusting the polymerization conditions to produce the uncured core polymer of the core/clad construction with a much reduced terminal vinyl content, preferably below 0.5 vinyl groups/1000 monomer units. This process improvement, in combination with selected addition of a combination of certain hindered phenols and hydrolytically stable organic phosphites, together produce a substantial improvement in the resistance to discoloration under photo-thermal conditions, while maintaining the resistance to discoloration under thermal conditions. The known process conditions which do not yield lower terminal vinyl content, in combination with the selected additives, also produce acrylic light pipe with greatly improved photo-thermal stability.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.