Mixed ionic electronic conductor coatings for redox electrodes
US6210832A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Sep 1, 1998 |
| Grant date | Apr 3, 2001 |
| Priority date | — |
| Expiry date | Sep 1, 2018 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02T10/70
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
Disclosed is a redox electrode for a battery cell that has a coating to mitigate plugging by precipitated discharge products. The coating comprises a mixed ionic electronic conductor (MIEC) which is applied to the surface of a redox electrode. The presence of the MIEC coating allows for rapid removal of discharge product precipitates from redox electrodes since it is capable of conducting both electrons and ions. As a result, the chemical action necessary to remove such precipitates may take place on both the electrolyte side of the precipitate and at the precipitate/electrode interface. MIEC coatings in accordance with the present invention may be composed of any suitable material having ionic conductivity for a metal ion in a negative electrode with which the redox electrode is to be paired in a battery cell, and reversible redox capacity. Examples include titanium sulfide (TiS.sub.2), iron sulfide (FeS.sub.2), and cobalt oxides.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.