Patent · US Expired

Emulsion copolymers from terminally unsaturated acrylic acid oligomers

US6248826A · kind A · utility

7Cited by
12References
12Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 16, 1999
Grant dateJun 19, 2001
Priority date
Expiry dateJul 16, 2019

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC01P2004/62
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

An aqueous dispersion of a copolymer formed by the emulsion polymerization of a monomer mixture including from 0.1 to 20% by weight of one or more terminally unsaturated carboxylic acid oligomers; from 80 to 99.9% by weight of at least two monomers selected from esters and amides of (meth)acrylic acid, vinyl esters of carboxylic acids, vinyl aromatic compounds, ethylenically unsaturated nitrites, vinyl halides, and non-aromatic hydrocarbons; and 0 to 10% by weight of other copolymerisable monomers is provided. The aqueous copolymer dispersion is polymerized in the presence of anionic surfactant and at an acid pH. Also provided is a method of preparing the aqueous copolymer dispersion. Aqueous copolymer dispersions including the terminally unsaturated carboxylic acid oligomers have low viscosities over a broad pH range and are useful in coating compositions, as binders for nonwovens, textiles, paper coatings, and as adhesives.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.