Patent · US Expired

Nanocomposites formed by onium ion-intercalated clay and rigid anhydride-cured epoxy resins

US6251980A · kind A · utility

75Cited by
83References
46Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMar 19, 1999
Grant dateJun 26, 2001
Priority date
Expiry dateMar 19, 2019

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC01P2006/33
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant onium ion spacing agent and an anhydride-curable epoxy resin. The intercalant onium ion spacing agent converts the interlayer region of the layered materials from hydrophilic to hydrophobic, therefore, the anhydride-curable epoxy resin can be easily intercalated into the interlayer spacing. The co-presence of the co-intercalant anhydride-curable epoxy resin in the interlayer space provides surprising increase in glass transition temperature for anhydride-curable epoxy resin matrix polymer/co-intercalant compounded nanocomposites. The nanocomposites (e.g., epoxy-clay) prepared from the intercalants demonstrate enhanced mechanical, thermal and chemical resistance compared with pristine polymer matrices.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.