Patent · US Expired

Bath for electrolytic reduction of alumina and method therefor

US6258247A · kind A · utility

6Cited by
11References
19Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 9, 1999
Grant dateJul 10, 2001
Priority date
Expiry dateFeb 9, 2019

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC25C3/18
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

An electrolytic bath for use during the electrolytic reduction of alumina to aluminum. The bath comprises a molten electrolyte having the following ingredients: (a) AlF.sub.3 and at least one salt selected from the group consisting of NaF, KF, and LiF; and (b) about 0.004 wt. % to about 0.2 wt. %, based on total weight of the molten electrolyte, of at least one transition metal or at least one compound of the metal or both. The compound may be, for example, a fluoride, oxide, or carbonate. The metal can be nickel, iron, copper, cobalt, or molybdenum. The bath can be employed in a combination that includes a vessel for containing the bath and at least one non-consumable anode and at least one dimensionally stable cathode in the bath. Employing the bath of the present invention during electrolytic reduction of alumina to aluminum can improve the wetting of aluminum on a cathode by reducing or eliminating the formation of non-metallic deposits on the cathode.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.