Process for producing polypropylene from C3 olefins selectively produced by a two stage fluid catalytic cracking process

US6258257A · kind A · utility

Assignee

• EXXONMOBIL RESEARCH AND ENGINEERING COMPANY · US

Inventors

• George A. Swan, III · Baton Rouge, US
• Michael W. Bedell · Baton Rouge, US
• Paul K. Ladwig · Dover, US
• John E. Asplin · Houston, US
• Gordon F. Stuntz · Baton Rouge, US
• William A. Wachter · Baton Rouge, US
• B. Erik Henry · Katy, US

Key dates

• Filing date: Mar 2, 2000
• Grant date: Jul 10, 2001
• Expiry date: Mar 2, 2020

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C10G2400/20
• WIPO field: Basic materials chemistry
• WIPO sector: Chemistry

Abstract

A process for producing polymers from olefins selectively produced by a two stage process for selectively producing C.sub.2 to C.sub.4 olefins from a gas oil or resid is disclosed herein. The gas oil or resid is reacted in a first stage comprising a fluid catalytic cracking unit wherein it is converted in the presence of conventional large pore zeolitic catalyst to reaction products, including a naphtha boiling range stream. The naphtha boiling range stream is introduced into a second stage comprising a process unit containing a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feed is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500 to 650.degree. C. and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles …