Process for preparing protective-colloid-stabilized vinyl ester or vinyl ester-ethylene polymers in the form of their aqueous dispersions
US6262163A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Mar 29, 1999 |
| Grant date | Jul 17, 2001 |
| Priority date | — |
| Expiry date | Mar 29, 2019 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F2/24
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The invention relates to a process for preparing protective-colloid-stabilized vinyl ester or vinyl ester-ethylene polymers in the form of their aqueous dispersions by emulsion polymerization in the presence of one or more protective colloids, which comprises carrying out the polymerization in the presence of a hydrophobic but silane-free protective colloid based on (meth)acrylate polymers with from 80 to 95% by weight, based on the total weight of the copolymer, of acrylic or methacrylic esters of aliphatic alcohols having from 1 to 12 carbon atoms, and from 5 to 20% by weight, based on the total weight of the copolymer, of ethylenically unsaturated mono- or dicarboxylic acids, and with a glass transition temperature Tg of the copolymer of from 60 to 120.degree. C., and with a Fikentscher K value of the copolymer of from 20 to 50.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.