Patent · US Expired

Activation method of titanium silicalite

US6288004A · kind A · utility

5Cited by
9References
14Claims
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Key dates

Filing dateMay 5, 1999
Grant dateSep 11, 2001
Priority date
Expiry dateMay 5, 2019

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/582
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A method is described for improving the catalytic performances of titanium silicalite having formula (I) by the activation of the catalyst (I) in an aqueous medium with hydrogen peroxide, in the presence of precursors of fluoride ions or anionic species containing fluorine. The activated catalyst (I) is particularly useful in oxidation processes with hydrogen peroxide of organic substrates and, in particular, in hydroxylation reactions of aromatic compounds, amoximation reactions of carbonyl compounds, epoxidation reactions of olefinic compounds and oxidation reactions of nitrogenated compounds.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.