Process for the preparation of 1,1,1,2-tetrafluoroethane
US6288293A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jun 21, 1993 |
| Grant date | Sep 11, 2001 |
| Priority date | — |
| Expiry date | Jun 21, 2013 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C17/206
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
The invention relates to a process for the preparation of 1,1,1,2-tetrafluoroethane from 1,1,1-trifluoro-2-chloroethane and hydrogen fluoride in the gas phase, in which a catalyst containing chromium and magnesium is used which is obtainable by precipitating chromium(III) hydroxide by reacting 1 mol of a water-soluble chromium(III) salt with at least 1.5 mol of magnesium hydroxide or magnesium oxide in the presence of water, the reaction mixture is made into a paste containing chromium hydroxide and a magnesium salt, and the paste is then dried and treated with hydrogen fluoride at temperatures of 20 to 500.degree. C.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.