Patent · US Expired

Methods for removing catalyst after oxidation of hydrocarbons

US6294689A · kind A · utility

1Cited by
69References
55Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 19, 2000
Grant dateSep 25, 2001
Priority date
Expiry dateSep 19, 2020

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/10
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

This invention relates to oxidative methods for controlling the oxidation of a class of compounds, including hydrocarbons, such as cyclohexane for example, alcohols, such as cyclohexanol for example, ketones, such as cyclohexanone for example, and peroxides, such as cyclohexylhydroperoxide for example, to intermediate oxidation products, such as adipic acid for example, by the removing the catalyst, such as cobalt compounds for example, from the oxidation mixture, outside the oxidation zone, after the oxidation has taken place at least partially. The catalyst is at least partially precipitated by following the steps of changing the temperature to be within a specific range, and sequentially reducing the water level to such a degree that causes the catalyst to precipitate. The precipitated catalyst is thereafter preferably filtered from the oxidation mixture and recycled to the oxidation zone.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.