Metal catalyzed synthesis of hyperbranched ethylene and/or .alpha.-olefin polymers
US6303717A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Feb 3, 1998 |
| Grant date | Oct 16, 2001 |
| Priority date | — |
| Expiry date | Feb 3, 2018 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S526/933
- WIPO fieldBasic materials chemistry
- WIPO sectorChemistry
Abstract
Oily hyperbranched polymers derived from ethylene, propylene, butene and/or a C.sub.5 -C.sub.24 .alpha.-olefin, and a method for their synthesis, are disclosed. The polymers have non-regular microstructures and are characterized by a ratio ({character pullout})of methyl hydrogens centered around 0.85 ppm on the 1H-NMR spectra of the polymers relative to total aliphatic hydrogens of from about 0.40 to about 0.65 for polymers derived from ethylene or butene, and a ratio ({character pullout})of from greater than 0.50 to about 0.65 for polymers derived from propylene. A method for grafting hyperbranched polymers derived from ethylene, propylene, butene and/or a C.sub.5 -C.sub.24 .alpha.-olefin onto aromatic rings in organic molecules and polymers, and the resulting grafted materials, are also disclosed. The hyperbranched polymers and grafted materials are useful, for example, as lubricants and lubricant additives.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.