Method for polymerizing conjugated diolefins (dienes) with catalysts based on cobalt compounds in the presence of vinylaromatic solvents
US6310151A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jan 12, 2001 |
| Grant date | Oct 30, 2001 |
| Priority date | — |
| Expiry date | Jan 12, 2021 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F36/04
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
Conjugated diolefins, optionally in combination with other unsaturated compounds which may be copolymerized with the diolefins, are polymerized by performing the polymerization of the diolefins in the presence of catalysts based on cobalt compounds, organoaluminum compounds and modifiers in the presence of aromatic vinyl compounds at temperatures of -30.degree. C. to +80.degree. C. By means of the process according to the invention, it is possible straightforwardly to produce solutions of polydiolefins, such as polybutadiene, having different 1,2 unit contents in aromatic vinyl compounds, which solutions may then, for example, be further processed to yield ABS or HIPS.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.