Patent · US Expired

Adsorbents, method for the preparation and method for the separation of unsaturated hydrocarbons for gas mixtures

US6315816A · kind A · utility

10Cited by
4References
39Claims
0Family size

Assignees

Inventors

Key dates

Filing dateOct 4, 1999
Grant dateNov 13, 2001
Priority date
Expiry dateOct 4, 2019

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S95/90
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A group of solid adsorbents in the form of powder, granules or pellets having improved adsorptive capacity and selectivity for ethylene and/or propylene is disclosed. These adsorbents comprise (a) a silver compound and (b) a bentonite clay support bulk of which comprises SiO.sub.2 and Al.sub.2 O.sub.3 and the rest being oxides of Fe, Ca, Mg, Na and K and having sufficiently high surface area on which the silver compound is dispersed or impregnated. The support may be pretreated by polymer solutions to impart sufficient mechanical strength as measured by attrition loss. Mechanical strength may also be improved by pre-heating the support. These adsorbents are highly stable and are capable of reversibly adsorbing substantial quantity of ethylene and/or propylene at room temperature. The rates of adsorption of ethylene and/or propylene are also very high in these adsorbents, which is believed to be due to the synergistic interaction between the components of the novel composition of the present invention.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.