Patent · US Expired

Process for the direct oxidation of olefins to olefin oxides

US6323351A · kind A · utility

9Cited by
15References
45Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 9, 1999
Grant dateNov 27, 2001
Priority date
Expiry dateDec 9, 2019

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/52
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A process and catalysts for the direct oxidation of an olefin having three or more carbon atoms, such as propylene, by oxygen to an olefin oxide, such as propylene oxide. The process involves contacting the olefin under reaction conditions with oxygen in the presence of hydrogen and a catalyst. The catalyst contains silver and titanium, optionally gold, and optionally, at least one promoter element selected from Group 1, Group 2, zinc, cadmium, the lanthanide rare earths, and the actinide elements. Suitable supports include titanium dioxide, titanium dioxide on silica, titanosilicates, promoter metal titanates, titanium dispersed on silica and promoter metal silicates.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.