Patent · US Expired

Process for producing adamantanols

US6333438A · kind A · utility

1Cited by
2References
14Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 14, 2000
Grant dateDec 25, 2001
Priority date
Expiry dateJul 14, 2020

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P10/20
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A process for efficiently separating and recovering a ruthenium compound used as the catalyst in the production of adamantanols. The adamantanols are produced by hydroxylating an adamantane compound in the presence of a ruthenium compound and a salt of hypochlorous acid in a water/organic solvent two-phase system. The hydroxylation product liquid is added with an oxidizing agent to allow the ruthenium compound to be extracted into the organic phase. The ruthenium compound is separated and recovered from the organic phase. Alternatively, the ruthenium compound is back-extracted into the aqueous phase by adding an aqueous alkali solution to the organic phase. Then, the ruthenium compound is separated and recovered from the aqueous phase.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.