Patent · US Expired

Crosslinking process

US6340719B1 · kind B1 · utility

15Cited by
66References
32Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 29, 1999
Grant dateJan 22, 2002
Priority date
Expiry dateDec 29, 2019

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T428/2896
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A process for crosslinking a melt-processed polymer composition comprises the steps of (a) forming a polymerizable mixture comprising (i) at least one monoethylenically-unsaturated monomer or prepolymer and (ii) at least one monoethylenically-unsaturated, blocked mono- or polyisocyanate that is thermally stable at a selected melt processing temperature range and that is thermally deblockable at and above a deblocking temperature that is higher than the selected melt processing temperature range; (b) exposing the polymerizable mixture to transmissive energy to polymerize the mixture to form a polymer composition comprising polymerized units derived from the blocked mono- or polyisocyanate; (c) melt processing the polymer composition at the selected melt processing temperature range to form a melt-processed polymer composition; and (d) during melt processing or thereafter, increasing the temperature of the melt-processed polymer composition to the deblocking temperatures in the presence of at least one isocyanate-reactive crosslinking agent, to effect crosslinking of the melt-processed polymer composition.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.