Patent · US Expired

Polymerization catalyst having a phosphinimine ligand

US6342463B1 · kind B1 · utility

44Cited by
2References
12Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 25, 2000
Grant dateJan 29, 2002
Priority date
Expiry dateFeb 25, 2020

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F110/02
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

This invention is a solution process for the preparation of high molecular weight ethylene copolymers comprising contacting olefin monomers, with a catalyst system at a polymerization temperature at or above about 80° C. with a catalyst system comprising an unbridged Group 4 metal compound having a monocyclopentadienyl ligand, a phosphinimine ligand and at least one uninegative, activation reactive ligand. The process can be practiced at a reaction temperature of at least 80° C. to obtain high number average molecular weight polymer.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.