Processing for preparing salts of dialkylphosphinic acids

US6355832B1 · kind B1 · utility

Assignee

• Clariant Corporation · DE

Inventors

• Norbert Weferling · Hürth, DE
• Hans-Peter Schmitz · Mönchengladbach, DE
• Gunter Kolbe · Kerpen, DE

Key dates

• Filing date: Mar 10, 2000
• Grant date: Mar 12, 2002
• Expiry date: Mar 10, 2020

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C07F9/30
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

The invention relates to a process for preparing salts of dialkylphosphinic acids, which comprisesa) reacting alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof with olefins in the presence of a free-radical initiator to give dialkylphosphinic acids and/or alkali metal salts thereof andb) reacting the dialkylphosphinic acids and/or alkali metal salts thereof obtained according to a) with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkylphosphinate salts. The invention likewise relates to the use of the metal dialkylphosphinate salts prepared by the process according to the invention for preparing flame retardants.