Catalyst and method for the production of polytetrahydrofuran
US6362312B1 · kind B1 · utility
Assignee
Inventors
Key dates
| Filing date | Apr 10, 2000 |
| Grant date | Mar 26, 2002 |
| Priority date | — |
| Expiry date | Apr 10, 2020 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08G65/2657
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
In a process for preparing polytetrahydrofuran, polytetrahydrofuran copolymers or diesters or monoesters thereof comprises polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer over an acid-activated calcium montmorillonite as catalyst, the calcium montmorillonite has a BET surface area of at least 300 m2/g, an acidity of at least 0.02 mmol/g at pKa<−3 and a pore volume of at least 0.40 cm3/g for pore sizes in the range from 30 to 200 å.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.