Method for preparing polyorganosiloxanes (POS) with thiol functions, POS obtainable by this method and their use particularly in rubber materials
US6372843B1 · kind B1 · utility
Assignee
Inventors
Key dates
| Filing date | Apr 19, 2000 |
| Grant date | Apr 16, 2002 |
| Priority date | — |
| Expiry date | Apr 19, 2020 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08L2205/03
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The present invention relates to a process for preparing multifunctionalized polyorganosiloxanes (POSs) comprising alkoxyl functional siloxyl units and siloxyl units each having an SH functional group, which consists in introducing the SH functional group by the reaction of H2S on a precursor POS of formula: A—(RXSiO)a—(RYSiO)b—B where R is especially a C1-C6 alkyl radical, X is a C1-C15 alkoxyl radical, Y is a C2-C30 hydrocarbon group which includes an ethylenically unsaturated group from which the SH functionality derives, a is a number ranging from 1 to 150, b is a number ranging from 1 to 150, the number a+b ranging from 2 to 300 and A and B are terminal groups which are selected respectively, from, in particular, on the one hand (R)3SiO— radicals taken alone or as mixtures with (R)2XSiO— and/or R(X)2SiO— and/or (X)3SiO— radicals and on the other hand —Si(R)3 radicals taken alone or as mixtures with —SiX(R)2 and/or —Si(X)2R and/or —Si(X)3 radicals.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.