Nitrate/nitrite-free manufacturing of glass with selenium
US6408650B1 · kind B1 · utility
Assignee
Inventors
Key dates
| Filing date | Dec 10, 1997 |
| Grant date | Jun 25, 2002 |
| Priority date | — |
| Expiry date | Dec 20, 2018 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S501/905
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
The invention is a method of retaining selenium in a lass containing selenium by including a manganese compound and not including nitrates or nitrites routinely used in the industry to retain selenium. Particularly, a preferred embodiment involves manufacturing a gray soda-lime-silica glass composition including selenium as a colorant, the components of the gray soda-lime-silica glass have colorants consisting essentially of: greater than 0.9 to 1.9 wt. % total iron oxide as Fe2O3; 0.10 to 1.00 wt. % manganese compound as MnO2; 0.0010 to 0.0060 wt. % selenium as Se; 0.002 to 0.025 wt. % cobalt oxide as Co, and 0 to 1.0 wt. % titanium oxide as TiO2 which are combined and melted to make the glass composition. The glass composition has at 4.0 mm. thickness: 10 to 55% light transmittance using Illuminant A, less than 25% ultra violet transmittance, and less than 50% infra red transmittance.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.