Heterocyclyl ligand containing ruthenium and osmium catalysts
US6417363B1 · kind B1 · utility
Assignee
Inventors
Key dates
| Filing date | May 26, 2000 |
| Grant date | Jul 9, 2002 |
| Priority date | — |
| Expiry date | May 26, 2020 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07F15/0046
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Penta- and hexa-coordinated, bridged ruthenium and osmium catalysts of the formula wherein Me is ruthenium or osmium; L1 and L2 are neutral ligands having electron donor properties;X is an anionic ligand; Y is oxygen or sulphur; A is a direct bond, C1-C4alkylene or C2-C4alkylidene;Z is a direct bond, oxygen, sulphur or the groups wherein R1 and R2 are hydrogen or hydrocarbon radicals; their preparation and their us in the synthesis of polymers, in the ring-closure metathesis of diolefins, in the cross metathesis of olefins and in the isomerisation of olefins are disclosed.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.