Patent · US Expired

Oxidation process for the production of alkenes and carboxylic acids

US6476261B2 · kind B2 · utility

24Cited by
2References
7Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 28, 2001
Grant dateNov 5, 2002
Priority date
Expiry dateSep 28, 2021

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/582
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A process for the oxidation of a C2 to C4 alkane to produce the corresponding alkene and carboxylic acid which process comprises contacting in an oxidation reaction zone, said alkane, molecular oxygen-containing gas, and optionally, at least one of the corresponding alkene and water, in the presence of at least two catalysts each active, with different selectivities, for the oxidation of the alkane to the corresponding alkene and carboxylic acid, to produce a product stream comprising said alkene, carboxylic acid and water, and in which process the molar ratio of alkene to carboxylic acid produced in said oxidation reaction zone is adjusted or maintained at a pre-determined value by controlling the relative proportions of the at least two catalysts in said oxidation reaction zone. Such an oxidation process may be used in an integrated process, such as for the manufacture of ethyl acetate or vinyl acetate.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.