Patent · US Expired

Nanocomposites for high barrier applications

US6486252B1 · kind B1 · utility

6Cited by
127References
18Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 22, 1999
Grant dateNov 26, 2002
Priority date
Expiry dateJun 22, 2019

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08K9/04
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

The present invention relates to a composition comprising (i) a layered clay material that has been cation-exchanged with an organic cation salt represented by Formula (I): wherein M is nitrogen or phosphorous, X− is a halide, hydroxide, or acetate anion, R1 is a straight or branched alkyl group having at least 8 carbon atoms, and R2, R3, and R4 are independently hydrogen or a straight or branched alkyl group having 1 to 22 carbon atoms; and (ii) at least one expanding agent, wherein the cation-exchanged clay material contains platelet particles and the expanding agent separates the platelet particles. The present invention also relates to a composite comprising a polymer having dispersed therein a composition of this invention. Preferred polymers for use in the composite include polyesters. The composite of the present invention shows vastly improved platelet separation as evidenced by higher than previously reported basal spacing.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.