Patent · US Expired

Late transition metal catalyst complexes and oligomers therefrom

US6501000B1 · kind B1 · utility

41Cited by
35References
20Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 4, 2000
Grant dateDec 31, 2002
Priority date
Expiry dateApr 4, 2020

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C2531/22
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

The invention is directed towards a composition comprising the formula LMX(X′)n wherein n equals 0 or 1; X and X′ are independently selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert; M is selected from the group consisting of nickel, palladium, and platinum and L is a nitrogen-containing bidentate ligand with more than two nitrogen atoms. The composition possesses a tetrahedral or pseudo-tetrahedral structure. The invention also provides a method for using the composition in conjunction with an activating cocatalyst to form short chain &agr;-olefins.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.