Patent · US Expired

Composition and method for acidizing wells and equipment without damaging precipitation

US6534448B1 · kind B1 · utility

20Cited by
43References
20Claims
0Family size

Assignee

Inventor

Key dates

Filing dateNov 2, 2000
Grant dateMar 18, 2003
Priority date
Expiry dateFeb 24, 2021

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S507/934
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

An acidizing composition and a method of acidizing a hydrocarbon bearing subterranean formation in the presence of ferric ions are provided. The acidizing composition includes an aqueous mineral acid solution, an electron donor agent and an electron transfer agent, the electron transfer agent being a source of molybdenum ions. When the aqueous mineral acid solution includes hydrochloric acid in an amount greater than approximately 17% by weight, the acidizing composition further includes a supplemental electron transfer agent, the supplemental electron transfer agent being a source of iodide ion or iodine. The electron donor agent and electron transfer agent function together to reduce ferric ion present in the mineral acid solution to ferrous ion which in turn prevents ferric hydroxide and/or free sulfur from precipitating out of the solution and reduces the formation of sludge in crude oil in the formation.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.