Patent · US Expired

Catalysts for the production of unsaturated acids or esters

US6544924B1 · kind B1 · utility

18Cited by
7References
16Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 1, 2000
Grant dateApr 8, 2003
Priority date
Expiry dateDec 1, 2020

Classification

  • Technology area (CPC B)Performing Operations; Transporting
  • CPC primaryB01J35/651
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

The production of ethylenically unsaturated acids or esters by the catalytic reaction of an alkanoic acid or ester, especially methyl propionate, with formaldehyde, and a catalyst therefor wherein the catalyst comprises a porous high surface area silica containing 1-10% by weight of an alkali metal, especially cesium, (expressed as metal) and having compounds of at least one modifier element selected from boron, magnesium, aluminum, zirconium and hafnium dispersed in the pores of said silica in such amount that the catalyst contains a total of 0.25 to 2 gram atoms of primary modifier element per 100 moles of silica.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.