Patent · US Expired

Method of polycarbonate preparation

US6548623B2 · kind B2 · utility

40Cited by
2References
38Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 24, 2001
Grant dateApr 15, 2003
Priority date
Expiry dateJul 24, 2021

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G64/307
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Polycarbonates containing low or undetectable levels of Fries rearrangement product may be prepared by the melt reaction of a dihydroxy aromatic compound such as bisphenol A with an ester-substituted diaryl carbonate such as the diaryl carbonate of methyl salicylate, bis-methyl salicyl carbonate. Low levels of Fries product are obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reaction using diphenyl carbonate.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.